The particulate 7Be/210Pbxs and 234Th/210Pbxs activity ratios as tracers for tidal-to-seasonal particle dynamics in the Gironde estuary (France): implications for the budget of particle-associated contaminants.

The short-lived natural radionuclides (7)Be (T(1/2)=53 days), (234)Th(xs) (T(1/2)=24.1 days) and (210)Pb(xs) (T(1/2)=22.3 years), i.e. (234)Th and (210)Pb in excesses of that supported within particles by the decay of their parent isotopes, were analysed in suspended particulate matter (SPM) to study the particle dynamics in the Gironde fluvial estuarine system (France), strongly impacted by heavy metal pollution. From surveys of this land-ocean interface in 2006 and 2007, we established a times series of these radioisotopes and of their activity ratios ((7)Be/(210)Pb(xs) and (234)Th/(210)Pb(xs) ARs) in particles sampled under different hydrological conditions. The particulate (7)Be/(210)Pb(xs) AR varies along the fluvial estuarine system mainly due to variations in (7)Be activities, controlled by riverine, oceanic and atmospheric inputs and by resuspension of old (7)Be-deficient sediments. These processes vary with river discharge, tidal cycle and season. Therefore, seasonal particle transport processes can be described using variations of the SPM (7)Be/(210)Pb(xs) ARs. During high river discharge, the SPM (7)Be/(210)Pb(x) ARs decrease from river to the ocean. The turbidity maximum zone (TMZ) is dispersed and the particles, and the associated contaminants, are rapidly transported from river to coastal waters, without significant retention within the TMZ. During low river discharge, the TMZ intrudes into the fluvial estuary, and the lowest (7)Be/(210)Pb(x) ARs are observed there due to resuspension of (7)Be-deficient sediments. Away from the TMZ, from the middle to lower estuary, SPM (7)Be/(210)Pb(x) ARs increase, indicating that the particles have been recently tagged with (7)Be. We explain this trend as being caused by marine input of dissolved radionuclides, as traced by SPM (234)Th/(210)Pb(xs) ARs, followed by scavenging in the estuary. This result indicates that particle transport models based on (7)Be and trace-metal budgets must consider oceanic dissolved inputs as an additional source of (7)Be and, possibly, of contaminants to estuaries.