Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water.

Chem Commun (Camb)

Department of Chemistry and Biochemistry, Jackson State University, 1400 J. R. Lynch Street, P.O. Box 17910, Jackson, MS 39212, USA.

Published: September 2010

Structural characterization of a sulfate complex with an azamacrocycle suggests that one sulfate is encapsulated in the macrocyclic cavity with eight hydrogen bonds; a significant selectivity of the host was observed for sulfate over halides, nitrate and perchlorate as evaluated by (1)H NMR studies in water.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3056152PMC
http://dx.doi.org/10.1039/c0cc01699cDOI Listing

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