Applicability of a continuous-flow system inner-coated with S-doped titania for the photocatalysis of dimethyl sulfide at low concentrations.

J Environ Manage

Department of Environmental Engineering, Kyungpook National University, Sankeok-dong, Buk-gu, Daegu 702-701, Korea.

Published: October 2010

The present study investigated the photocatalytic activity of an S-doped TiO(2) photocatalyst with regards to dimethyl sulfide degradation under visible-light irradiation, along with its deactivation and reactivation. The dimethyl sulfide conversion was between 85% and 93% for the lowest relative humidity range (10-20%) and close to 100% for the two higher relative humidity ranges (45-55% and 80-90%). The conversion was also close to 100% for the two lowest input concentrations (0.039 and 0.195 ppm), while it was between 91% and 96% at 3.9 ppm and between 85% and 90% at 7.9 ppm. In contrast to the input concentration dependences on conversion, the calculated degradation rates increased as input concentrations increased. The dimethyl sulfide conversion at low concentrations (

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