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A hydridoirida-beta-diketone as an efficient and robust homogeneous catalyst for the hydrolysis of ammonia-borane or amine-borane adducts in air to produce hydrogen. | LitMetric
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A hydridoirida-beta-diketone as an efficient and robust homogeneous catalyst for the hydrolysis of ammonia-borane or amine-borane adducts in air to produce hydrogen.

Roberto Ciganda María A Garralda Lourdes Ibarlucea Elena Pinilla M Rosario Torres

Dalton Trans

Facultad de Química de San Sebastián, Universidad del País Vasco, Apdo. 1072, 20080, San Sebastián, Spain.

Published: August 2010

The first homogeneous metal-catalysed hydrolysis of ammonia-borane or amine-borane adducts for hydrogen generation, using a stable organometallic complex [IrHCl{(PPh(2)(o-C(6)H(4)CO))(2)H}], is reported.

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 Source
http://dx.doi.org/10.1039/c0dt00091dDOI Listing

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