Aim: This study evaluates the effect of single and multiple consecutive applications of adhesives on the tensile bond strength. The currently available adhesives follow either the total-etch or the self-etch concept. However, in both techniques the uniformity and thickness of the adhesive layer plays a significant role in the development of a good bond.
Materials And Methods: Sixty composite-dentin bonded specimens were prepared using a total-etch adhesive (Gluma) and another 60 using a self-etch adhesive (AdheSE). Each group was further divided into six subgroups based on the number of applications, i.e., single application and multiple (2, 3, 4, 6, and 8) applications. The tensile bond strength was tested with the Instron universal testing machine. The values were analyzed with one-way ANOVA and multiple range tests by Tukey's HSD procedure to identify those subgroups that had significantly higher bond strength.
Results: The results indicate that with total-etch adhesive the bond strength increases significantly as the number of applications are increased from one to two or from two to three", for self-etch adhesive the bond strength obtained with two applications is significantly higher than that with one application. However, for both adhesive systems, there was a decrease in the tensile bond strength values with further applications.
Conclusion: We conclude that, in the clinical setting, the application of multiple coats of total etch adhesive improves bonding.
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http://dx.doi.org/10.4103/0972-0707.55618 | DOI Listing |
Mater Horiz
January 2025
Department of Materials Science, University of Michigan, Ann Arbor, Michigan 48109, USA.
It is difficult to intuit how electronic structure features-such as band gap magnitude, location of band extrema, effective masses, -arise from the underlying crystal chemistry of a material. Here we present a strategy to distill sparse and chemically-interpretable tight-binding models from density functional theory calculations, enabling us to interpret how multiple orbital interactions in a 3D crystal conspire to shape the overall band structure. Applying this process to silicon, we show that its indirect gap arises from a competition between first and second nearest-neighbor bonds-where second nearest-neighbor interactions pull the conduction band down from Γ to X in a cosine shape, but the first nearest-neighbor bonds push the band up near X, resulting in the characteristic dip of the silicon conduction band.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Chemistry, Dr. Harisingh Gour Vishwavidyalaya (A Central University), Sagar-470003, India.
In a recent communication (A. Shivhare, B. Dehariya, S.
View Article and Find Full Text PDFBeilstein J Org Chem
January 2025
Department of Chemistry, University of Rhode Island, 140 Flagg Rd, Kingston, RI 02881, USA.
The CFH group can act as a hydrogen bond donor, serving as a potential surrogate for OH or SH groups but with a weaker hydrogen bond donation ability. Here, we describe a series of CFH group-containing moieties that facilitate hydrogen bond interactions. We survey hydrogen bond donation ability using several established methods, including H NMR-based hydrogen bond acidity determination, UV-vis spectroscopy titration with Reichardt's dye, and H NMR titration using tri--butylphosphine oxide as a hydrogen bond acceptor.
View Article and Find Full Text PDFMicrosc Res Tech
January 2025
Department of Restorative and Prosthetic Dental Sciences, College of Dentistry, Dar Al Uloom University, Riyadh, Saudi Arabia.
Effect of different root canal irrigation regimes microbubble emulsion (MBE) via riboflavin photosensitizer (RFP), cerium oxide (CeO) nanoparticles (NPs), and Nd: YAP laser on antibacterial efficiency, microhardness (MH), smear layer (SL) removal efficacy, and push-out bond strength (PBS) of AH plus sealer to canal dentin. Sixty single-rooted teeth were selected, disinfected, and categorized into four groups based on the type of disinfection. Following disinfection, a pair of samples were randomly selected and visualized under scanning electron microscope (SEM) for SL evaluation.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu, 210094, China.
After cyclo-pentazolate anion, a 5/6 fused structure of N is constructed, and four novel nitrogen-rich ionic compounds are assembled on its basis. The results of the quantum calculations revealed an uneven distribution of electrons on cyclo-N , with significant charge density near the N5/N9 atoms and an ADCH charge of -0.425.
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