Stabilized alpha-helix-catalyzed enantioselective epoxidation of alpha,beta-unsaturated ketones.

Org Lett

Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8582, Japan.

Published: August 2010

Chiral cyclic alpha-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of alpha,beta-unsaturated ketones and the alpha-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.

Download full-text PDF

Source
http://dx.doi.org/10.1021/ol101435wDOI Listing

Publication Analysis

Top Keywords

enantioselective epoxidation
8
epoxidation alphabeta-unsaturated
8
alphabeta-unsaturated ketones
8
stabilized alpha-helix-catalyzed
4
alpha-helix-catalyzed enantioselective
4
ketones chiral
4
chiral cyclic
4
cyclic alpha-amino
4
alpha-amino acid
4
acid oligopeptide
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!