Reaction of BH(3)·NEt(3) with tris(trimethylsilyl)silylpotassium yielded the respective silylboranate. Abstraction of a hydride with B(C(6)F(5))(3) led to the neutral silylborane, which could be derivatised as an Et(3)N adduct. Treatment of the boranate with Cp(2)Ti(btmsa) resulted in exchange of THF coordinating to potassium by Cp(2)Ti(btmsa).
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The quest for silylhydroboranes: (Me(3)Si)(3)SiBH(2).
Dalton Trans
October 2010
Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010 Graz, Austria.
Reaction of BH(3)·NEt(3) with tris(trimethylsilyl)silylpotassium yielded the respective silylboranate. Abstraction of a hydride with B(C(6)F(5))(3) led to the neutral silylborane, which could be derivatised as an Et(3)N adduct. Treatment of the boranate with Cp(2)Ti(btmsa) resulted in exchange of THF coordinating to potassium by Cp(2)Ti(btmsa).
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