Synthesis of novel beta-diketonate bis(bipyridyl) Os(II) dyes for utilization of infrared light in dye-sensitized solar cells.

Chem Commun (Camb)

Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, 12-1 Ichigaya-funagawara, Shinjuku, Tokyo 162-0826, Japan.

Published: August 2010

Bis(bipyridyl) osmium(II) dyes having a beta-diketonate ligand were synthesized in order to utilize visible and infrared light for dye-sensitized solar cells. Compared to black dye, under AM 1.5 irradiation (100 mW cm(-2)), DSCs using our novel Os dyes exhibited a better spectral response in the near-IR region (by 1050 nm) and showed a higher J(SC) value of 23.7 mA cm(-2).

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http://dx.doi.org/10.1039/c0cc00749hDOI Listing

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