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MXene/PEDOT: PSS composite-modified electrode for electrochemical sensing of bilirubin by molecularly imprinted ortho-phenylenediamine.
Mikrochim Acta
January 2025
Applied Science Department, The NorthCap University, 122017, Gurugram, Haryana, India.
For the first time, a TiCT-MXene and poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate) (PEDOT: PSS) composite-modified electrode has been developed for electrochemical detection of the bilirubin (BR) by molecularly imprinted ortho-phenylenediamine (o-PD). BR is a biomarker for liver-related diseases. High levels of BR imply liver dysfunction; hence, its exact and rapid measurement is indispensable to its immediate diagnosis and treatment.
View Article and Find Full Text PDFAdvancing dynamic quantum crystallography: enhanced models for accurate structures and thermodynamic properties.
IUCrJ
January 2025
Faculty of Chemistry, University of Warsaw, Pasteura 1, Warsaw, 02-093, Poland.
X-ray diffraction (XRD) has evolved significantly since its inception, becoming a crucial tool for material structure characterization. Advancements in theory, experimental techniques, diffractometers and detection technology have led to the acquisition of highly accurate diffraction patterns, surpassing previous expectations. Extracting comprehensive information from these patterns necessitates different models due to the influence of both electron density and thermal motion on diffracted beam intensity.
View Article and Find Full Text PDFA High-Performance Electrochemical Sensor Based on Ni-Pt Bimetallic Nanoparticles doped Metal Organic Framework ZIF-8 for The Detection of Dopamine.
Chempluschem
January 2025
Université de Tours: Universite de Tours, Department of chemistry, 1 JARDIN MONTAIGNE 37300 JOUE LES TOURS, 37300, JOUE LES TOURS, FRANCE.
In this paper, microporous Zn-based zeolitic imidazolate framework with the sodalite cage structure (SOD-ZIF-8) was synthesized by the solvothermal method. Powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and N2 adsorption were employed to characterize the synthesized material. An ultra-sensitive electrochemical sensor based on highly dispersed bimetallic Ni-Pt nanoparticles immobilized on zeolitic metal-organic framework ZIF-8 for dopamine quantification is introduced for the first time.
View Article and Find Full Text PDFGene-Implanting by a Porphyrin Derivative to Establish Quasi-antennas into the Carbon Microspheres toward Superior Microwave Absorbing/Shielding Performance.
Langmuir
January 2025
Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, 16846-13114 Tehran, Iran.
Carbon microspheres (CMSs) are recognized as highly effective microwave absorbers due to their exceptional wave absorption properties. In this study, 5,10,15,20-tetrakis(4-aminophenyl)porphyrin, a metamaterial, was chemically bonded to CMSs─considered a conjugated carbon structure─using a 1,3-dibromopropane linker to explore the synergistic properties and microwave absorption capabilities of the synthesized composite. The synthesized structures were characterized by using X-ray diffraction, FE-SEM, Fourier transform infrared, diffuse reflectance spectroscopy, and VNA analyses.
View Article and Find Full Text PDFInvestigating the Synergistic Interactions Between AgNPs and NiCl on the Morpho-Physiological Trajectories of Zea mays L. Through Comprehensive Characterization at Seedling Stage.
Microsc Res Tech
January 2025
Department of Botany and Microbiology, College of Science, King Saud University, Riyadh, Saudi Arabia.
Green synthesis of nanoparticles (NPs) is preferred for its affordability and environmentally friendly approach. This study explored the synthesis and characterization of silver NPs (AgNPs) and examined their impact on the growth of Zea mays, both alone and in combination with nickel chloride (NiCl). A methanolic leaf extract was combined with silver nitrate to synthesize AgNPs.
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