The lineshape of light emission from a titanium vacuum arc was studied using a Fizeau interferometer coupled with an optical multichannel analyzer (OMA). A viewing geometry normal to the cathode surface was employed. Temperatures of ~3 x 10(5) K and ~3.5 x 10(4) K were obtained for titanium ions and titanium atoms present in the cathode spot, respectively. In light of results from previous work, a case is made for the latter temperature being the actual heavy species temperature in the cathode spot.
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http://dx.doi.org/10.1364/AO.29.005145 | DOI Listing |
PLoS One
January 2025
Department of Computer Science, Khalifa University, Abu Dhabi, UAE.
A methodology is proposed, which addresses the caveat that line-of-sight emission spectroscopy presents in that it cannot provide spatially resolved temperature measurements in non-homogeneous temperature fields. The aim of this research is to explore the use of data-driven models in measuring temperature distributions in a spatially resolved manner using emission spectroscopy data. Two categories of data-driven methods are analyzed: (i) Feature engineering and classical machine learning algorithms, and (ii) end-to-end convolutional neural networks (CNN).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Sun Yat-Sen University, School of Chemistry and Chemical Engineering, 135 West Xingang Road, 510275, Guangzhou, CHINA.
Metal-organic complexes with long afterglow luminescence have attracted extensive attention due to potential applications in display, sensing and information security. However, most of the metal-organic complex long afterglow materials reported so far are limited to the use of UV light as the excitation source, and the ambiguity of the structure-activity relationship makes the development of metal-organic complexes extremely limited. Herein, a series of metal-organic complexes with ultralong emission lifetime is constructed by coordination assembly of Zn(II) with three isomers.
View Article and Find Full Text PDFSmall
January 2025
Department of Materials Science and Engineering, and Center for Functional Photonics (CFP), City University of Hong Kong, Hong Kong SAR, 999077, P. R. China.
Metal halide perovskite nanoplatelets (NPls) possess ultra-narrow photoluminescence (PL) bands tunable over the entire visible spectral range, which makes them promising for utilization in light-emitting diodes (LEDs) with spectrally pure emission colors. This calls for development of synthetic methods toward perovskite NPls with a high degree of control over both their thickness and lateral dimensions. A general strategy is developed to obtain such monodisperse CsPbI NPls through the control over the halide-to-lead ratio during heating-up reaction.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
CMA Earth System Modeling and Prediction Centre (CEMC), China Meteorological Administration, Beijing 100081, China.
Vegetation fires release a large fraction of light-absorbing components, which can contribute to the melting of snowpack and alpine glaciers. However, the relationship between variability in fire emissions and alpine glacier melting on the Third Pole (TP) remains poorly understood. This study provides evidence that carbon emissions from windward vegetation fires play a crucial role in comprehending glacier melting on the TP, particularly during the months of intense vegetation fires from March to May for monsoon-dominated glaciers and from June to October for westerlies-dominated glaciers.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Modulation of optical properties through smart protein matrices is exemplified by a few examples in nature such as rhodopsin (absorption wavelength tuning) and the green fluorescence protein (emission), but in general, the scope found in nature for the matrix-controlled photofunctions remains rather limited. In this review, we present cyclophane-based supramolecular host-guest complexes for which electronic interactions between the cyclophane host and mostly planar aromatic guest molecules can actively modulate excited-state properties in a more advanced way involving both singlet and triplet excited states. We begin by highlighting photofunctional host-guest systems for on-off fluorescence switching and chiroptical functions using bay-functionalized perylene bisimide cyclophanes.
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