Responsive lanthanide complexes demonstrate differentiated modulated luminescence output upon exposure to metal di-cations in aqueous solution.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c0cc00210kDOI Listing

Publication Analysis

Top Keywords

lanthanide complexes
8
luminescent probes
4
probes based
4
based water-soluble
4
water-soluble dual-emissive
4
dual-emissive lanthanide
4
complexes metal
4
metal ion-induced
4
ion-induced modulation
4
modulation near-ir
4

Similar Publications

Recent advances in optical heavy water sensors.

Chem Commun (Camb)

January 2025

Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China.

DO and HO, as two important solvents with very similar properties, play a pivotal role in nuclear industrial production, life and scientific research. Unfortunately, DO and HO are highly susceptible to contamination by each other, so effective qualitative and quantitative analyses of both are necessary. This review comprehensively discusses the progress in optical sensing for the detection of a trace amount of HO in heavy water or , mainly including five types of analytical systems: inorganic nanocrystals, carbon-based nanomaterials, lanthanide complexes, organic polymers, and organic small molecules.

View Article and Find Full Text PDF

Single-molecule Magnet Properties of Silole- and Stannole-ligated Erbium Cyclo-octatetraenyl Sandwich Complexes.

Chemistry

January 2025

University of Sussex, Department of Chemistry, School of Life Sciences, BN1 9QJ, Brighton, UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND.

The synthesis, structures and magnetic properties of an η5-silole complex and an η5-stannole complex of erbium are reported. The sandwich complex anions [(η5-CpSi)Er(η8-COT)]- and [(η5-CpSn)Er(η8-COT)]-, where CpSi is [SiC4-2,5-(SiMe3)2-3,4-Ph2]2- (1Si), CpSn is [SnC4-2,5-(SiMe3)2-3,4-Me2]2- (1Sn) and COT = cyclo-octatetraenyl, were obtained as their [K(2.2.

View Article and Find Full Text PDF

The blood-brain-barrier prevents many imaging agents and therapeutics from being delivered to the brain that could fight central nervous system diseases such as Alzheimer's disease and strokes. However, techniques such as the use of stapled peptides or peptide shuttles may allow payloads through, with bioconjugation achieved bio-orthogonal tetrazine/norbornene click chemistry. A series of lanthanide-tetrazine probes have been synthesised herein which could be utilised in bio-orthogonal click chemistry with peptide-based delivery systems to deliver MRI agents through the blood-brain-barrier.

View Article and Find Full Text PDF

While several ligand systems support uranium across a range of oxidation states, spanning more than two oxidation states in a conserved coordination geometry is uncommon among structurally authenticated complexes. Imidophosphorane ligands significantly stabilize high-valent lanthanide and actinide complexes. Here, we report a series of homoleptic uranium imidophosphorane complexes, spanning the +4, +5 and +6 oxidation states in a four-coordinate pseudotetrahedral ligand field.

View Article and Find Full Text PDF

Ratiometric lanthanide coordination polymers (Ln-CPs) are advanced materials that combine the unique optical properties of lanthanide ions (e.g., Eu, Tb, Ce) with the structural flexibility and tunability of coordination polymers.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!