The development of a unique noncontact temperature measurement device utilizing rotating analyzer ellipsometry is described. The technique circumvents the necessity of spectral emissivity estimation by direct measurement concomitant with radiance brightness. Simultaneous determinations of dielectric constants and refractive indices allow changes in the physical and chemical state of a heated surface to be monitored. The results of optical property measurements at 633 nm as functions of temperature between 1000 and 2500 K for eight transition metals including Hf, Ir, Mo, Nb, Pd, Pt, Ta, and V are presented together with preliminary results of oxidation studies on iridium.
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http://dx.doi.org/10.1364/AO.28.001885 | DOI Listing |
Environ Monit Assess
January 2025
College of the Environment and Ecology, Xiamen University, Xiamen, 361102, Fujian, China.
Synthetic organic dye such as methylene blue (MB) is non-biodegradable and highly toxic, released from textile wastewater. This work investigates the applicability of Ni@ZnO polymer nanocomposite for MB removal from the wastewater. To understand their differences before and after MB adsorption, composites' surface morphology was characterized by various techniques including scanning electron microscope (SEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), Fourier transformation infrared (FT-IR) and UV-Vis spectrophotometer.
View Article and Find Full Text PDFMikrochim Acta
January 2025
USST-UH International Joint Laboratory for Tumor Diagnosis and Energy Treatment, University of Shanghai for Science and Technology, Shanghai, 200093, China.
Ternary heterojunction BiS/MoS/BiMoO was designed as a signal probe to develop a dual signal amplification strategy empowered electrochemical biosensor for sensitive miRNA-21 detection by combining with catalytic hairpin assembly (CHA). The combination of the BiS/MoS/BiMoO heterojunction as a tracer indication probe and the CHA amplification strategy not only took fully use of the highly dense nanowire interwoven structure and superior active region of the probe, but also endowed the ability to improve the molecular hybridization efficiency by collision, which significantly avoided the cumbersome chain design and greatly simplified the step-by-step construction of the electrode surface. Hairpin H1 was first added dropwise to the gold nanoparticle-decorated electrode surface, and then opened by the introduced miRNA-21 to initiate the specific hybridization.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
USTC: University of Science and Technology of China, Environmental Science and Engineering, CHINA.
The development of advanced catalysts frequently employs trial-and-error methods and is lack of highly controlled synthesis, resulting in unsatisfactory development efficiency and performance. Here we propose a data-driven prediction coupled with precise synthesis strategy to accelerate the development of single-atom catalysts (SACs) for efficient water purification. The data-driven approach enables the rapid screening and prediction of high-performance SACs from 43 metals-N4 structures comprising transition and main group metal elements, followed by validation and structural modulation for improved performance through a highly controllable hard-template method.
View Article and Find Full Text PDFNMR Biomed
March 2025
Center for Image Sciences, University Medical Center Utrecht, Utrecht, The Netherlands.
Deuterium (H) and phosphorus (P) magnetic resonance spectroscopy (MRS) are complementary methods for evaluating tissue metabolism noninvasively in vivo. Combined H and P MRS would therefore be of interest for various applications, from cancer to diabetes. Loop coils are commonly used in X-nuclei studies in the human body for both transmit and receive.
View Article and Find Full Text PDFChem Soc Rev
January 2025
Centre for Clean Energy Technology, School of Mathematical and Physical Sciences, Faculty of Science, University of Technology Sydney, City Campus, Broadway, NSW 2007, Australia.
The battery market is primarily dominated by lithium technology, which faces severe challenges because of the low abundance and high cost of lithium metal. In this regard, multivalent metal-ion batteries (MVIBs) enabled by multivalent metal ions ( Zn, Mg, Ca, Al, ) have received great attention as an alternative to traditional lithium-ion batteries (Li-ion batteries) due to the high abundance and low cost of multivalent metals, high safety and higher volumetric capacities. However, the successful application of these battery chemistries requires careful control over electrode and electrolyte chemistries due to the higher charge density and slower kinetics of multivalent metal ions, structural instability of the electrode materials, and interfacial resistance, This review comprehensively explores the recent advancements in electrode and electrolyte materials as well as separators for MVIBs, highlighting the potential of MVIBs to outperform Li-ion batteries regarding cost, energy density and safety.
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