Coordination chemistry approach for the end-to-end assembly of gold nanorods.

J Colloid Interface Sci

Institut Lavoisier de Versailles, CNRS-UMR 8180, PRES UniverSud, Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.

Published: September 2010

Gold nanorods synthesized by radiolysis were selectively end-functionalized by a fully conjugated thiol bearing a pendant terpyridine group; addition of ferrous ions led to the end-to-end 1D self-assembly of the nanorods. Similar results have been obtained when the preformed [(HStpy)Fe(tpySH)](2+) dithiol complex was directly added to the gold nanorods.

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http://dx.doi.org/10.1016/j.jcis.2010.05.050DOI Listing

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