AI Article Synopsis
- The reaction of silver(i) perchlorate with the ligand bisox in methanol results in a triply-interpenetrated sheet structure.
- On recrystallization from acetonitrile-diethyl ether, a hybrid structure with interpenetrated sheets and Ag(2)(bisox)(3) cages forms.
- Heating the material under vacuum leads to a rearrangement where the cages transform into sheets, involving a change in the conformation of the bisox ligands.
Article Abstract
The reaction of silver(i) perchlorate with the semi-rigid ligand 1,4-bis((3,5-dimethylisoxazol-4-yl)methyl)benzene (bisox) in methanol gives a triply-interpenetrated sheet structure, but a structure containing both interpenetrated sheets and Ag(2)(bisox)(3) cages is formed on recrystallisation from acetonitrile-diethyl ether. Rearrangement of the cages into sheets occurs on heating under vacuum, a process which involves a solid state change in conformation of the bisox ligands.
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| http://dx.doi.org/10.1039/c0cc00826e | DOI Listing |
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