Water reduction can be electrochemically promoted by zinc under very mild conditions, as demonstrated by the formation of the complex [Zn(H(2)O)(6)][Zn(3)(L)(3)(mu(3)-O)], whose anion consists of a Zn(3)O(4) cluster incorporating a mu(3)-oxo anion.
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| http://dx.doi.org/10.1039/c0cc00256a | DOI Listing |
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