Hg(2+) was found to specifically induce the aggregation of perylene bisimide in a "thymine-Hg(2+)-thymine" binding motif and the resultant aggregates showed a highly selective and sensitive turn-on fluorescence response for cysteine, with a detection limit down to 9.6 nM.
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http://dx.doi.org/10.1039/c0cc00630k | DOI Listing |
Polymers (Basel)
January 2025
Faculty of Materials Science and Engineering, Kyoto Institute of Technology, Sakyo, Kyoto 606-8585, Japan.
The transient dynamics of photocurrents for poly((4-diphenylamino)benzyl acrylate) (PDAA)-based photorefractive (PR) polymers sensitized with perylene bisimide derivative N,N'-diisopropylphenyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxyl bisimide (PBI) at various composition ratios were studied. The PR polymer included (4-(diphenylamino)phenyl)methanol (TPAOH) photoconductive plasticizer and (4-(azepan-1-yl)-benzylidene) malononitrile nonlinear optical dye as well, which are needed for inducing PR effects. All the photocurrents measured at 640 nm were well simulated by a two-trapping site model considering photocarrier generation and recombination processes of the charge transfer (CT) complex between PBI and PDAA.
View Article and Find Full Text PDFJ Org Chem
January 2025
Center for Nanosystems Chemistry (CNC), Universität Würzburg, Theodor-Boveri-Weg, 97074 Würzburg, Germany.
Chiral organic molecules with a complementing π-structure are highly desired to obtain materials with good semiconducting properties and pronounced chirality effects in the visible region. Herein, we introduce a novel design strategy to achieve an axially chiral and rigid perylene bisimide (PBI) dye by attaching the chirality-inducing 2,2'-biphenoxy moiety at one side of the bay area and the rigidity-inducing di--butylsilanediol bridge on the other side. This yielded a new bay-functionalized PBI derivative carrying the combination of a highly rigid and, simultaneously, an axially chiral perylene core.
View Article and Find Full Text PDFChemistry
December 2024
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, Assam, 781039, India.
This study presents a selenium-annulated perylene bisimide (PBI-Se) stabilizing room temperature columnar hexagonal phase with exceptionally low clearing temperature. The synthesis of this Se-annulated PBI (PBI-Se) was accomplished using the reductive Cadogan cyclization method, with the introduction of swallow tails to reduce the clearing temperature and improve solubility. In addition, the charge carrier mobility of the Se-bay annulated PBI is assessed by space charge limited current (SCLC) technique and juxtaposed with PBI as well as nitrogen and sulphur-bay-annulated PBIs.
View Article and Find Full Text PDFLangmuir
December 2024
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China.
Heparin is widely used to treat thrombosis because it is an effective anticoagulant. However, excessive use of heparin can lead to an increased risk of bleeding, which makes the quantitative detection of heparin very important. An amphiphilic perylene bisimide molecule (denoted PBI-9) was developed, which presented a near-infrared emission peak at 730 nm when it was aggregated.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Institut für Organische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.
Whilst energetic and kinetic aspects of folding processes are meanwhile well understood for natural biomacromolecules, the folding dynamics in so far studied artificial foldamer counterparts remain largely unexplored. This is due to the low energy barriers between their conformational isomers that make the dynamic processes undetectable with conventional methods such as UV/Vis absorption, fluorescence, and NMR spectroscopy, making such processes 'invisible'. Here we present an asymmetric perylene bisimide dimer (bis-PBI 1) that possesses conformational chirality in its folded state.
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