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A high triplet energy host is developed using a silane moiety, 9-(4-(triphenylsilyl)dibenzo[b,d]furan-2-yl)-9H-carbazole (SiDBFCz), is designed through extensive density functional theory (DFT) calculations to obtain appropriate hole and electron injection barriers. The chemical hardness and the charge transport characteristics are comprehensively investigated to realize a bipolar host with high triplet energy over 2.9 eV for deep blue phosphorescent organic light-emitting diodes (PHOLEDs).

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Organic materials for deep blue phosphorescent organic light-emitting diodes.

Adv Mater

June 2012

Department of Polymer Science and Engineering, Dankook University, Jukjeon-dong, Suji-gu, Yongin, Gyeonggi, Korea.

Recently, great progress has been made in the device performance of deep blue phosphorescent organic light-emitting diodes (PHOLEDs) by developing high triplet energy charge-transport materials, high triplet energy host and deep blue emitting phosphorescent dopant materials. A high quantum efficiency of over 25% and a high power efficiency of over 15 lm/W have already been achieved at 1000 cd m(-2) in the deep blue PHOLEDs with a y color coordinate less than 0.20.

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