We consider a system weakly interacting with a bath as a thermodynamic setting to establish a quantum foundation of statistical physics. It is shown that even if the composite system is initially in an arbitrary nonequilibrium pure quantum state, the unitary dynamics of a generic weak interaction almost always drives the subsystem into the canonical ensemble, in the usual sense of typicality. A crucial step is taken by assuming that the matrix elements of the interaction Hamiltonian have random phases, while their amplitudes are left unrestricted.
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http://dx.doi.org/10.1103/PhysRevLett.104.170402 | DOI Listing |
J Phys Condens Matter
January 2025
School of Physics Science and Engineering, Tongji University, siping road, Shanghai, 200092, CHINA.
Hybrid magnonics has attracted extensive attention for its potential applications in quantum information processing, especially following the discovery of strong coupling in magnon-magnon hybrid systems. In this paper, we studied the coupling phenomena between the left-handed (LH) and right-handed (RH) magnon modes in synthetic antiferromagnets (SAFs) with a tilted perpendicular magnetic anisotropy (PMA). By tilting the PMA at a certain angle from the film normal, we achieved strong magnon-magnon coupling without the need for an external magnetic field.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physics, Wolkite University, P. O. Box: 07, Wolkite, Ethiopia.
This study uses the Quantum ESPRESSO code to introduce Hubbard correction (U) to the density functional theory (DFT) in order to examine the effects of non-metals (C, F, N, and S) doping on the structural, electronic, and optical characteristics of rutile TiO. Rutile TiO is a substance that shows promise for use in renewable energy production, including fuels and solar energy, as well as environmental cleanup. Its wide bandgap, however, restricts their uses to areas with UV light.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Shenzhen University, College of Materials Science and Engineering, Xueyuan Avenue, 518000, Shenzhen, CHINA.
The development of pure-green organic emitters with ideal emission peak and ultra-narrow full-widths at half-maximum (FWHMs) remains a formidable challenge. Herein, we report two new green emitters, CNBN and MCNBN, which achieve extremely narrow FWHMs by synergistic rigid π-extension and cyano-substitution for sky-blue multi-resonance thermally activated delayed fluorescence (MR-TADF) core. The introduction of cyano groups induces red-shifts of emission to green region and dramatically minimize the FWHMs.
View Article and Find Full Text PDFLuminescence
January 2025
Pharmaceutical Analytical Chemistry Department, Faculty of Pharmacy, Al-Azhar University, Cairo, Egypt.
The environmental impact of chemicals used in aquaculture, particularly nitrofurantoin, has raised global concern. Nitrofurantoin, a broad-spectrum antimicrobial, is commonly used in aquaculture despite safety risks. Determination of nitrofurantoin in water samples of fish ponds is necessary to ensure the safety and quality of seafood.
View Article and Find Full Text PDFMolecules
January 2025
Department of Chemistry, Sapienza University of Rome, P. le Aldo Moro 5, 00185 Rome, Italy.
In this paper, we present a molecular dynamics study of the structural and dynamical properties of γ-valerolactone (GVL) both as a standalone solvent and in electrolyte formulations for electrochemistry applications. This study involves developing a new parameterization of a polarizable forcefield and applying it to simulate pure GVL and selected salt solutions. The forcefield was validated with experimental bulk data and quantum mechanical calculations, with excellent agreement obtained in both cases.
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