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Remarkable effect of phosphine on the reactivity of O,P-acetal--efficient substitution reaction of O,P-acetal. | LitMetric
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Remarkable effect of phosphine on the reactivity of O,P-acetal--efficient substitution reaction of O,P-acetal.

Hiromichi Fujioka Akihiro Goto Kazuki Otake Ozora Kubo Kenzo Yahata Yoshinari Sawama Tomohiro Maegawa

Chem Commun (Camb)

Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan.

Published: June 2010

The structure and electronic nature of the phosphine have a significant influence on not only the formation, but also the subsequent transformation of O,P-acetals. The O,P-acetals generated from tris(o-tolyl)phosphine [(o-tol)(3)P] underwent efficient substitution reactions with various nucleophiles.

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 Source
http://dx.doi.org/10.1039/c0cc00170hDOI Listing

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