Unprecedented open ended nitrogen doped carbon nanotubes prepared by direct pyrolysis of [Co(HTTG)(H(2)O)(2)](n) (TTG = N,N',N''-1,3,5-triazine-2,4,6-triyltris-glycine) show among the largest surface area of multiwalled nanotubes and high CO(2)/CH(4) adsorption selectivity which increases with increasing of nitrogen content.
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