Acetate-controlled demetalation in multiiron polyoxometalates: a triiron cluster trapped between beta- and gamma-Keggin isomers.

Dalton Trans

Institut für Festkörperforschung, Forschungszentrum Jülich GmbH, D-52425, Jülich, Germany.

Published: August 2009

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Acetate-induced demetalation of a {gamma-SiW(10)Fe(2)}-based dimer affords an acetato/hydroxo-bridged triiron cluster stabilized by two isomerically distinct Keggin units.

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http://dx.doi.org/10.1039/b905211aDOI Listing

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