AI Article Synopsis
- The review focuses on supramolecular compounds featuring organometallic half-sandwich complexes made from metals like Ir, Rh, and Ru, highlighting their diverse potential applications.
- It emphasizes the self-assembly of molecular shapes (rectangles, prisms, cages) using a stepwise construction method with specific rigid bifunctional ligands.
- The tutorial discusses in detail the synthetic techniques used to create these complexes and explores their structural and functional properties.
Article Abstract
Over the past decade, supramolecular compounds with organometallic Ir, Rh, Ru based half-sandwich complexes have received considerable attention as materials with a variety of potential applications. The major emphasis of this tutorial review lies on the self-assembly of such organometallic half-sandwich molecular rectangles, prisms and cages with half-sandwich corners and two different rigid bifunctional ligands using an approach of stepwise construction. Synthetic methods and the structural and functional properties of the target complexes are discussed in detail.
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| http://dx.doi.org/10.1039/b901649j | DOI Listing |
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