A facile photosynthesis of trans-dioxoruthenium(VI) porphyrins.

Chem Commun (Camb)

Department of Chemistry, Western Kentucky University, 1906 College Heights Blvd., Bowling Green, Kentucky, USA.

Published: June 2010

Photolysis of porphyrin-ruthenium(IV) dichlorate complexes with visible light results in homolytic cleavage of the O-Cl bond in the chlorates to form trans-dioxoruthenium(VI) species bearing either sterically encumbered or unencumbered porphyrin ligands.

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Source
http://dx.doi.org/10.1039/c003094eDOI Listing

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