Coordination complexes of previously observed intermediates, H(3)B.NMe(2)BH(2).NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B.NMe(2)H and H(3)B.NMeH(2) have been isolated and structurally characterised using the [Rh{PR'(2)(eta(2)-C(5)H(7))}](+) fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process.
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| http://dx.doi.org/10.1039/c003055d | DOI Listing |
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