Correlation of the scaling exponent gamma of the diffusivity-density function in viscous liquids with their elastic properties.

J Chem Phys

Department of Physics, Solid State Physics Section, University of Athens, Panepistimiopolis, 15784 Zografos, Athens, Greece.

Published: April 2010

Fundamental thermodynamical concepts and a solid-state point defect elastic model are used to formulate a diffusivity-density scaling function for viscous liquids. It is proved in a straightforward manner that the scaling exponent gamma describing the density scaling of the diffusivity is related with the pressure derivative of the isothermal bulk modulus.

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http://dx.doi.org/10.1063/1.3382645DOI Listing

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