Spontaneous chiral resolution of mer-[Co(II)(N,N,O-L3)2] enantiomers mediated by pi-pi interactions.

Chem Commun (Camb)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

Published: June 2010

Six possible isomers of mer-[M(II)(N,N,O-L)(2)] complex were observed in the solid state, in which spontaneous resolution of S,S-Lambda and R,R-Delta enantiomers of mer-[Co(N,N,O-L3)(2)] was achieved via pi-pi interactions.

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Source
http://dx.doi.org/10.1039/c002167aDOI Listing

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