The synthesis of silicon nanosheets for fabricating electronic devices, without using conventional vacuum processes and vapor deposition, is challenging and is anticipated to receive significant attention for a wide range of applications. Here, we report the synthesis of oxygen-free, phenyl-modified organosilicon nanosheets with atomic thickness. In organic solvents, a consequence of this new silicon structure is its uniform dispersion and the possibility of exfoliation into unilamellar nanosheets. Light-induced photocurrent in [Si(6)H(4)Ph(2)] was observed, leading to the possibility of various organosilicon nonamaterials with useful properties.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja100919d | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Chemical-Physical Synergistic Assembly of MXene/CNT Nanocoatings in Silicone Foams for Reliable Piezoresistive Sensing in Harsh Environments.
Small
December 2024
College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Key Laboratory of Silicone Materials Technology of Zhejiang Province, Hangzhou Normal University, Hangzhou, 311121, China.
Owing to their high sensitivity across a wide stress range, mechanical reliability, and rapid response time, flexible polymer foam piezoresistive sensors have been extensively used in various fields. The reliable application of these sensors under harsh environments, however, is severely limited by structural devastation and poor interfacial bonding between polymers and conductive nanoparticles. To address the above issues, robust MXene/CNT nanocoatings on the foam surface, where the chemical assembly of MXene nanosheets and the physical anchoring of CNTs lead to strong interfacial bonding, are designed and described, which endows foams with structural reliability and unexpected multi-functionalities without compromising their instinct properties.
View Article and Find Full Text PDFSingle-layer semiconductor-decorated flexible 2D protein nanosheets by engineered anchoring for efficient photocatalytic hydrogen production.
Int J Biol Macromol
March 2024
Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China. Electronic address:
Protein self-assembly can be accurately manipulated to form ordered nanostructures through various supramolecular forces. This strategy is expected to make significant breakthroughs in the field of new biomimetic functional materials. Specifically, the construction of photocatalytic systems on two-dimensional (2D) flexible protein nanosheets meets a great challenge.
View Article and Find Full Text PDFNatural lignocellulosic kapok fiber/MXene constructed hydrogel evaporators for high efficiency solar steam generation.
Int J Biol Macromol
March 2024
School of Chemistry and Chemical Engineering, Yangzhou University, No 180, Road Siwangting, Yangzhou, Jiangsu 225002, China. Electronic address:
Solar-driven interfacial evaporation (SDIE) is a green and sustainable technique for desalination. Hydrogel composite evaporators have been widely used for SDIE, but it is still challenging for the hydrogel evaporators to achieve uniform distribution of the light absorbing nanomaterials and at the same time possess satisfactory evaporation rate, durability and environmental applicability. We developed a 3D hydrogel evaporator with an asymmetric structure for high-efficiency SDIE.
View Article and Find Full Text PDFSelective adsorption of nitrate in water by organosilicon quaternary ammonium salt modified derived nickel-iron layered double hydroxide: Adsorption characteristics and mechanism.
J Colloid Interface Sci
December 2023
School of Chemistry and Materials Science, Heilongjiang University, Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, Harbin 150080, China.
Nitrate (NO) is a widespread pollutant in the water environment. Due to its physicochemical properties, such as negative monovalent charge, traditional adsorption treatment processes have low selectivity for NO removal, resulting in low removal efficiency of NO by adsorbents in the presence of interfering ions. Therefore, to improve the adsorption selectivity and efficiency of NO.
View Article and Find Full Text PDFDirect Observation of Photon Induced Giant Band Renormalization in 2D PdSe Dichalcogenide by Transient Absorption Spectroscopy.
Small
November 2023
Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen, 518060, China.
Insight into fundamental light-matter interaction as well as underlying photo-physical processes is crucial for the development of novel optoelectronic devices. Palladium diselenide (PdSe ), an important representative of emerging 2D noble metal dichalcogenides, has gain considerable attention owing to its unique optical, physical, and chemical properties. In this study, 2D PdSe nanosheets (NSs) are prepared using the liquid-phase exfoliation method.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!