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Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy). | LitMetric
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Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy).

Dong-Ping Li Tian-Wei Wang Cheng-Hui Li Dong-Sheng Liu Yi-Zhi Li Xiao-Zeng You

Chem Commun (Camb)

State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China.

Published: May 2010

A series of mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)(3)L] [Ln = Dy(1), Sm(2), Eu(3), Gd(4), and Tb(5), L = (S,S)-2,2'-Bis(4-benzyl-2-oxazoline)] were synthesized and characterized. Among these complexes, complex 1 represents the first example of mononuclear lanthanide complexes displaying single-ion magnet behavior and ferroelectricity.

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 Source
http://dx.doi.org/10.1039/b924547bDOI Listing

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