Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water.

Claire Besson Zhuangqun Huang Yurii V Geletii Sheri Lense Kenneth I Hardcastle Djamaladdin G Musaev Tianquan Lian Anna Proust Craig L Hill

Chem Commun (Camb)

Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, UPMC Univ. Paris 06, Case 42, 4 place Jussieu, 75005 Paris, France.

Published: April 2010

The tetraruthenium-substituted polyoxometalate Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)] was synthesized and structurally, spectroscopically and electrochemically characterized; it was shown to be a catalyst for visible-light-induced water oxidation.

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http://dx.doi.org/10.1039/b926064a	DOI Listing

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