Brine channels are formed in sea ice under certain constraints and represent a habitat of different microorganisms. The complex system depends on a number of various quantities as salinity, density, pH value, or temperature. Each quantity governs the process of brine channel formation. There exists a strong link between bulk salinity and the presence of brine drainage channels in growing ice with respect to both the horizontal and vertical planes. We develop a suitable phenomenological model for the formation of brine channels both referring to the Ginzburg-Landau theory of phase transitions as well as to the chemical basis of morphogenesis according to Turing. It is possible to conclude from the critical wave number on the size of the structure and the critical parameters. The theoretically deduced transition rates have the same magnitude as the experimental values. The model creates channels of similar size as observed experimentally. An extension of the model toward channels with different sizes is possible. The microstructure of ice determines the albedo feedback and plays therefore an important role for large-scale global circulation models.
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http://dx.doi.org/10.1103/PhysRevE.81.036106 | DOI Listing |
Extremophiles
January 2025
Microbiology Laboratory, Department of Botany (DST-FIST and UGC-DRS Funded), Institute of Science, Visva-Bharati (A Central University), Santiniketan, West Bengal, 731235, India.
To fish-out novel salt-tolerance genes, metagenomic DNA of moderately saline sediments of India's largest hypersaline Sambhar Lake was cloned in fosmid. Two functionally-picked clones helped the Escherichia coli host to tolerate 0.6 M NaCl.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
The precise and rapid extraction of lithium from salt-lake brines is critical to meeting the global demand for lithium resources. However, it remains a major challenge to design ion-transport membranes with accurate recognition and fast transport path for the target ion. Here, we report a triazine covalent organic framework (COF) membrane with high resolution for Li and Mg that enables fast Li transport while almost completely inhibiting Mg permeation.
View Article and Find Full Text PDFJ Colloid Interface Sci
April 2025
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China. Electronic address:
Developing efficient and cost-effective rare earth element-based electrocatalysts for water splitting remains a significant challenge. To address this, interface engineering and charge modulation strategies were employed to create a three-dimensional coral-like CeF/MoO heterostructure electrocatalyst, grown in situ on the multistage porous channels of carbonized sugarcane fiber (CSF). Integrating abundant CeF/MoO heterostructure interfaces and numerous oxygen vacancy defects significantly enhanced the catalyst's active sites and molecular activation capabilities.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Department of Civil and Environmental Engineering, University of California, Berkeley, Berkeley, California 94720, United States.
In this work, we analyzed the effects of mineral scaling on the performance of a 3D interfacial solar evaporator, with a focus on the cations relevant to lithium recovery from brackish water. The field has been rapidly moving toward resource recovery applications from brines with higher cation concentrations. However, the potential complications caused by common minerals in these brines other than NaCl have been largely overlooked.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Institute for Frontier Materials, Deakin University, Geelong, VIC, 3216, Australia.
Interfacial solar steam generation (ISSG) employed for seawater desalination and wastewater purification shows great promise to alleviate global freshwater scarcity. However, simultaneous optimization of water transfer direction in a cost-effective and reliable ISSG to balance thermal localization, salt accumulation, and resistance to oilfouling represents a rare feat. Herein, inspired by seabird beaks for unidirectional water transfer, eco-friendly and cost-effective plant extracts, sodium alginate, and tannic acid, are selected for crafting an innovative Sodium Alginate-Tannic Acid Hemispheric Evaporator (STHE).
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