In this paper we report on the influence of different geometric and boundary constraints on nonlocal (spatially inhomogeneous) effects in wormlike micellar systems. In a previous paper, nonlocal effects were observable by measuring the local rheological flow curves of micelles flowing in a microchannel under different pressure drops, which appeared to differ from the flow curve measured using conventional rheometry. Here we show that both the confinement and the boundary conditions can influence those nonlocal effects. The role of the nature of the surface is analyzed in detail using a simple scalar model that incorporates inhomogeneities, which captures the flow behavior in both wide and confined geometries. This leads to an estimate for the nonlocal "diffusion" coefficient (i.e., the shear curvature viscosity) which corresponds to a characteristic length from 1 to 10 microm.
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Sci Total Environ
January 2025
School of Resource and Environmental Science, Wuhan University, Wuhan 430079, China.
Forest age structures have been substantially affected by natural disturbances and anthropogenic activities worldwide. Their changes can significantly influence local and nonlocal climate through both the biogeochemical and biophysical processes. However, numerous studies have focused on the biogeochemical effect of forest age changes whereas the biophysical effect has received far less attention.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States.
Subsurface oxygen in oxide-derived copper catalysts significantly influences CO activation. However, its effect on the molecular charging process, the key to forming the CO intermediate, remains poorly understood. We employ many-body perturbation theory to investigate the impact of the structural factors induced by the subsurface oxygen on the charged activation of CO.
View Article and Find Full Text PDFQuant Imaging Med Surg
January 2025
Henan Key Laboratory of Imaging and Intelligent Processing, Information Engineering University, Zhengzhou, China.
Background: Photon-counting computed tomography (CT) is an advanced imaging technique that enables multi-energy imaging from a single scan. However, the limited photon count assigned to narrow energy bins leads to increased quantum noise in the reconstructed spectral images. To address this issue, leveraging the prior information in the spectral images is essential.
View Article and Find Full Text PDFACS Photonics
January 2025
Laboratory of Nanoscience for Energy Technologies (LNET), Faculty of Engineering (STI), Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne 1015, Switzerland.
Circular dichroism (CD) can distinguish the handedness of the chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest thermal CD (TCD) for chiral detection, leveraging the temperature difference in the chiral sample when subjected to right- and left-circularly polarized excitations.
View Article and Find Full Text PDFInorg Chem
January 2025
Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan.
Transition metal carbonyl and transition metal dinitrogen are fundamental chemical complexes in many important biological and catalytic processes. Interestingly, binding between a transition metal (TM) atom and carbonyl or dinitrogen results in spin state change. However, no study has evaluated the spin-orbit (SO) effect along the association pathway of any TM-CO or TM-N bond.
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