We present results demonstrating the occurrence of changes in the collective dynamics of a Hamiltonian system which describes a confined microplasma characterized by long-range Coulomb interactions. In its lower energy regime, we first detect macroscopically the transition from a "crystallinelike" to a "liquidlike" behavior, which we call the "melting transition." We then proceed to study this transition using a microscopic chaos indicator called the smaller alignment index (SALI), which utilizes two deviation vectors in the tangent dynamics of the flow and is nearly constant for ordered (quasiperiodic) orbits, while it decays exponentially to zero for chaotic orbits as exp[-(lambda(1)-lambda(2))t], where lambda(1)>lambda(2)>0 are the two largest Lyapunov exponents. During the melting phase, SALI exhibits a peculiar stairlike decay to zero, reminiscent of "sticky" orbits of Hamiltonian systems near the boundaries of resonance islands. This alerts us to the importance of the Deltalambda=lambda(1)-lambda(2) variations in that regime and helps us identify the energy range over which "melting" occurs as a multistage diffusion process through weakly chaotic layers in the phase space of the microplasma. Additional evidence supporting further the above findings is given by examining the GALI(k) indices, which generalize SALI (=GALI(2)) to the case of k>2 deviation vectors and depend on the complete spectrum of Lyapunov exponents of the tangent flow about the reference orbit.
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Angew Chem Int Ed Engl
December 2024
Sichuan University - Wangjiang Campus: Sichuan University, Chemistry, 29 Wangjiang Rd, 610064, Chengdu, CHINA.
Polyhydroxyalkanoates (PHAs) have attracted broad interest as promising sustainable materials to address plastic pollution and resource scarcity. However, the chemical synthesis of stereoregular PHAs via ring-opening polymerization (ROP) has long been an elusive endeavor. In this contribution, we exploited a robust spiro-salen yttrium complex (Y3) as the catalyst to successfully prepare syndiotactic PHAs with diverse pendent groups.
View Article and Find Full Text PDFJ Photochem Photobiol B
December 2024
School of Biological Sciences, Indian Association for the Cultivation of Science, Kolkata, West Bengal, India. Electronic address:
Exposure to ultraviolet radiation, which leads to the formation of mutagenic and cytotoxic DNA lesions such as cyclobutane pyrimidine dimers (CPDs) and 6-4 photoproducts (6-4 PPs), can be potentially fatal. The way UVA forms DNA lesions and alters DNA topology and mechanics is still unclear, unlike the cases of UVC and UVB. Herein, Atomic Force Microscopy (AFM) and AFM-based Force Spectroscopy (AFS) have been employed to investigate the topological and mechanical properties of single DNA molecules, bare or E.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600036, India.
In this study, a new lightweight Al-Ti-Ta alloy was developed through a synergistic approach, combining CALPHAD methodology and entropy-driven design. Following compositional optimization, the AlTiTa (at.%) alloy was fabricated and isothermally heat-treated at 475 °C for 24 h to attain equilibrium.
View Article and Find Full Text PDFPhys Rev Lett
October 2024
Université Sorbonne Paris Nord, Laboratoire de Physique des Lasers, CNRS UMR 7538, 99 avenue Jean-Baptiste Clément, F93430 Villetaneuse, France.
Soft Matter
October 2024
Northwestern Institute on Complex Systems and ESAM, Northwestern University, Evanston, IL 60208, USA.
We present the linear response theory for an elastic solid composed of active Brownian particles with intrinsic individual chirality, deriving both a normal mode formulation and a continuum elastic formulation. Using this theory, we compute analytically the velocity correlations and energy spectra under different conditions, showing an excellent agreement with simulations. We generate the corresponding phase diagram, identifying chiral and achiral disordered regimes (for high chirality or noise levels), as well as chiral and achiral states with mesoscopic-range order (for low chirality and noise).
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