Suspensions containing noncolloidal aluminum particles in a Newtonian carrier liquid and the effects of shear history on the rheological properties of suspensions are investigated showing a critical concentration phi(c), which is close to the "freezing" packing fraction of spherical particle suspensions. An apparent liquid-to-solid transition was clearly found for suspensions below phi(c) via transient step shear after long shear history as well as via the large amplitude oscillatory shear flow with controlled shear stress. The microstructures or the local flow characteristics of suspensions with phi
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http://dx.doi.org/10.1103/PhysRevE.80.061404 | DOI Listing |
Methods Mol Biol
December 2024
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Hong Kong, China.
Membraneless organelles (MLOs) formed via protein phase separation have garnered significant attention recently due to their relevance to cellular physiology and pathology. However, there is a lack of tools available to study their behavior and control their bioactivity in complex biological systems. This chapter describes a new optogenetic tool based on water-soluble chlorophyll protein (WSCP), a red light-induced singlet oxygen-generating protein, to control synthetic MLOs.
View Article and Find Full Text PDFNatl Sci Rev
December 2024
Department of Electrical and Electronic Engineering, Research Institute for Smart Energy (RISE), Photonic Research Institute (PRI), The Hong Kong Polytechnic University, Hong Kong 999077, China.
Solid additive engineering has been intensively explored on morphology tuning for highly efficient all-polymer solar cells (all-PSCs), a promising photovoltaic technology towards multi-scenario application. Although the nano-fibrillar network of the active layer induced by additive treatment is confirmed as the key factor for power conversion efficiency (PCE) of all-PSCs, its formation mechanism is not clearly revealed, for lack of precise and convincing real-time observation of crystallization and phase separation during the liquid-to-solid transition process of spin-coating. Herein we report an grazing incidence wide-angle/small-angle X-ray scattering (GIWAXS/GISAXS) screening that reveals the fact that naphthalene derived solid additives can suppress the aggregation of the polymer acceptor (PY-IT) at the beginning stage of spin coating, which provides sufficient time and space for the polymer donor (PM6) to form the fibril structure.
View Article and Find Full Text PDFACS Nano
December 2024
Department of Plant and Environmental Sciences, Weizmann Institute of Science, Rehovot 7610001, Israel.
Nat Chem
November 2024
Laboratory of Physical Chemistry and Soft Matter, Wageningen University and Research, Wageningen, the Netherlands.
ChemSusChem
November 2024
Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, Vuorimiehentie 1, Espoo, 02150, Finland.
Lignin-carbohydrate complexes (LCCs) present a unique opportunity for harnessing the synergy between lignin and carbohydrates for high-value product development. However, producing LCCs in high yields remains a significant challenge. In this study, we address this challenge with a novel approach for the targeted production of LCCs.
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