Liquid-to-solid transition of concentrated suspensions under complex transient shear histories.

Phys Rev E Stat Nonlin Soft Matter Phys

Department of Polymer Science and Engineering, Shanghai Jiao Tong University, Advanced Rheology Institute, Shanghai 200240, People's Republic of China.

Published: December 2009

Suspensions containing noncolloidal aluminum particles in a Newtonian carrier liquid and the effects of shear history on the rheological properties of suspensions are investigated showing a critical concentration phi(c), which is close to the "freezing" packing fraction of spherical particle suspensions. An apparent liquid-to-solid transition was clearly found for suspensions below phi(c) via transient step shear after long shear history as well as via the large amplitude oscillatory shear flow with controlled shear stress. The microstructures or the local flow characteristics of suspensions with phiphi(c) are still different according to the Fourier Transform Rheological analysis. Although suspensions with phiphi(c) disappears after preshear.

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http://dx.doi.org/10.1103/PhysRevE.80.061404DOI Listing

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