The extraordinary light transmission effect (EOT) through sub-wavelength nanoapertures in opaque metal films has lead to observation of a wide variety of exciting new optical phenomena. This remarkable effect is generally related to the interaction of the light with the extended plasmonic resonances on the surface of the metal film and localized surface plasmons in the apertures. On the other hand, there is little conceptual understanding for controlling the localized surface plasmonic behavior of the individual apertures and their coupling to the extended surface plasmons. In this letter, we present an intuitive and straightforward picture of the extra-ordinary light transmission phenomena based on basic antenna principles for plasmonic excitations and coupling of these plasmonic excitations in complex nano-apertures. Our quasi-static model remarkably well explains our experimental measurements in shape anisotropic structures with unique properties controlled by adjusting the size and the geometry of the apertures. Our approach puts forward new design principles for potential applications ranging from subwavelength optoelectronics and data storage to bio/chemical sensing.
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http://dx.doi.org/10.1166/jnn.2010.2045 | DOI Listing |
Discov Nano
January 2025
Department of Chemical Engineering, Military Technical College (MTC), Cairo, Egypt.
The world is now facing a water scarcity crisis due to waste, pollution, and uneven distribution of freshwater resources, which are limited. Thus, the creation of innovative, economical, and effective methods for purifying water is crucial. Here, the photo-assisted degradation of methylene blue (MB) dye under visible light and UV was achieved by using RGO photocatalyst loaded with ZnCuFeO in three different loaded 10%, 20%, and 30% called MRGO 10, MRGO 20, and MRGO 30.
View Article and Find Full Text PDFJ Food Drug Anal
December 2024
School of Pharmacy, College of Pharmacy, Taipei Medical University, Taipei 11031, Taiwan.
The rapid development of delivery systems for cosmetics has revealed two critical challenges in the field: enhancing the solubility of active ingredients and ensuring the stability of natural materials used in cosmetics. Nanoemulsion technology has emerged as an indispensable solution for addressing these challenges, not only enhancing the stability of cosmetics but also improving the solubility of pharmaceuticals and active ingredients with poor solubility. Nanoemulsion formulations have reinforced stability and amended the bioavailability of hydrophobic drugs.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Department of Electronic Engineering, Tsinghua University, Beijing 100084, China.
Fano resonance is achieved by tuning two coupled oscillators and has exceptional potential for modulating light dispersion. Here, distinct from the classical Fano resonances achieved through photonics methodologies, we introduce the Fano resonance in epsilon-near-zero (ENZ) media with novel electromagnetic properties. By adjusting the background permeability of the ENZ host, the transmission spectrum exhibits various dispersive line shapes and covers the full range of Fano parameter q morphologies, from negative to positive infinity.
View Article and Find Full Text PDFBiomacromolecules
January 2025
Polymer Research Centre and Centre for Advanced Functional Materials, Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Nadia, Mohanpur 741246, West Bengal, India.
The present investigation aims to develop a reactive oxygen species (ROS) and esterase-responsive biodegradable mannosylated polyurethane to effectively deliver the encapsulated antileishmanial drug amphotericin B (AmB) selectively to infected macrophage cells. Owing to suitable amphiphilic balance, the as-synthesized glycosylated polyurethane () with aryl boronic ester-based diol () moiety as ROS-trigger, water-soluble mannose pendants, and fluorescent 4,4-difluoro-4-bora-3a,4a-diaza--indacene (BODIPY) chain ends for bioimaging formed nanoaggregates in an aqueous medium as confirmed by H NMR spectroscopy, dynamic light scattering (DLS), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and critical aggregation concentration (CAC) measurements. Aided by two endogenous stimuli present in phagolysosome, ROS and esterase, AmB-encapsulated polymeric nanoaggregates as drug delivery vehicles achieved an efficient reduction of both and intracellular amastigote burden compared to the free AmB.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Chemistry, Federal University of São Paulo (UNIFESP), Diadema, SP, Brazil.
This study aims to use superparamagnetic iron oxide nanoparticles (SPIONs), specifically magnetite (FeO), to deliver deflazacort (DFZ) and ibuprofen (IBU) to Duchenne muscular dystrophy-affected (DMD) mouse muscles using an external magnetic field. The SPIONs are synthesized by the co-precipitation method, and their surfaces are functionalized with L-cysteine to anchor the drugs, considering that the cysteine on the surface of the SPIONs in the solid state dimerizes to form the cystine molecule, creating the FeO-(Cys)-DFZ and FeO-(Cys)-IBU systems for tests. The FeO nanoparticles (NPs) were characterized by Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), dynamic light scattering (DLS), and magnetic measurements.
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