High-yield synthesis and properties of symmetrical comb-like ZnO nanostructures on aluminum foil substrate.

J Nanosci Nanotechnol

Department of Chemistry, Faculty of Science, Advanced Materials and Nano-Engineering Laboratory, Najran University, P.O. Box 1988, Najran 11001, Kingdom of Saudi Arabia.

Published: April 2010

AI Article Synopsis

  • Highly-symmetrical ZnO nanostructures were produced in large quantities on aluminum foil using a non-catalytic thermal evaporation method at 440°C, employing metallic zinc powder and oxygen.
  • The nanostructures feature a ribbon-like stem with nanorod and nanowire arrays uniformly attached, confirmed through detailed morphological studies.
  • Characterization techniques like X-ray diffraction and photoluminescence indicate that these nanocombs are crystalline, exhibiting good optical properties and a proposed growth mechanism for their formation.

Article Abstract

Highly-symmetrical well-crystallized comb-like ZnO nanostructures were grown in a very large-quantity on the aluminum foil via non-catalytic thermal evaporation method by using metallic zinc powder in the presence of oxygen at low temperature of 440 degrees C. Detailed morphological investigations revealed that the as-grown combs are made with a ribbon-like stem and aligned nanorod/nanowire arrays attached uniformly and nicely along one side of the ribbon-like stem. The X-ray diffraction (XRD) pattern and high-resolution transmission electron microscopy (HRTEM) revealed that the as-grown nanocombs are crystalline and possessing a wurtzite hexagonal phase. The optical properties were observed by room-temperature photoluminescence (PL) and Raman-scattering which exhibited good optical properties for the as-grown products. A plausible growth mechanism has also been proposed for the formation of highly symmetrical comb-like ZnO nanostructures.

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http://dx.doi.org/10.1166/jnn.2010.1922DOI Listing

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