Natural abundance solid-state 95Mo MAS NMR of MoS2 reveals precise 95Mo anisotropic parameters from its central and satellite transitions.

Chem Commun (Camb)

Instrument Centre for Solid-State NMR Spectroscopy, Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark.

Published: March 2010

AI Article Synopsis

  • The study presents detailed measurements for the quadrupole coupling and chemical shift anisotropy of molybdenum-95 (95Mo) in molybdenum disulfide (MoS₂).
  • These measurements were obtained through analysis of a complex 14.1 T magic angle spinning (MAS) NMR spectrum, which shows both central and satellite transitions.
  • The reported values are significant due to their large magnitude, indicating important properties of the material at the atomic level.

Article Abstract

Precise values are reported for a quite large (95)Mo quadrupole coupling and an unusually large (95)Mo chemical shift anisotropy in MoS(2), values that have been retrieved by analysis of a well-resolved, highly complex 14.1 T (95)Mo MAS NMR spectrum displaying both the central and satellite transitions.

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http://dx.doi.org/10.1039/b926699bDOI Listing

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