Trapping of atomic hydrogens in cage-shaped silsesquioxanes by electric discharge.

Chem Commun (Camb)

Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan.

Published: March 2010

A simple and safe technique which is based on glow discharge is demonstrated for stable encapsulation of H atoms in cage-shaped silsesquioxanes at room temperature, leading to the encapsulation yield of ca. 10(-4) H atoms per molecule for 10-minute discharging, much faster than the conventional gamma-ray irradiation technique.

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http://dx.doi.org/10.1039/b917165gDOI Listing

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