In semiconducting nanowires, both zinc blende and wurtzite crystal structures can coexist. The band structure difference between the two structures can lead to charge confinement. Here we fabricate and study single quantum dot devices defined solely by crystal phase in a chemically homogeneous nanowire and observe single photon generation. More generally, our results show that this type of carrier confinement represents a novel degree of freedom in device design at the nanoscale.
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Dalton Trans
January 2025
Department of Chemistry, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain.
This perpective delves into the emerging field of matere bonds, a novel type of noncovalent interaction involving group 7 elements such as manganese, technetium, and rhenium. Matere bonds, a new member of the σ-hole family where metal atoms act as electron acceptors, have been shown experimentally and theoretically to play significant roles in the self-assembly and stabilization of supramolecular structures both in solid-state and solution-phase environments. This perspective article explores the physical nature of these interactions, emphasizing their directionality and structural influence in various supramolecular architectures.
View Article and Find Full Text PDFACS Mater Lett
January 2025
Department of Materials and London Centre for Nanotechnology, Imperial College London, South Kensington Campus, Exhibition Road, SW7 2AZ London, United Kingdom.
Quantum technologies using electron spins have the advantage of employing chemical qubit media with tunable properties. The principal objective of material engineers is to enhance photoexcited spin yields and quantum spin relaxation. In this study, we demonstrate a facile synthetic approach to control spin properties in charge-transfer cocrystals consisting of 1,2,4,5-tetracyanobenzene (TCNB) and acetylated anthracene.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), State Key Laboratory of Chemical Engineering, Haihe Laboratory of Sustainable Chemical Transformations, Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering & Technology, Tianjin University, Tianjin, 300072, P. R. China.
CO hydrogenation to methanol using green hydrogen derived from renewable resources provides a promising method for sustainable carbon cycle but suffers from high selectivity towards byproduct CO. Here, we develop an efficient PdZn-ZnO/TiO catalyst by engineering lattice dislocation structures of TiO support. We discover that this modification orders irregularly arranged atoms in TiO to stabilize crystal lattice, and consequently weakens electronic interactions with supported active phases.
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing WUT Nano Key Lab, Wuhan, Hubei, 430070, China.
The irreversible lattice oxygen release is the primary issue in layered oxide cathodes which is generally attributed to a consecutive phase transition with less lattice oxygen content. Herein, an anomalous metal segregation pathway is observed in oxygen vacancy defective layered cathodes, which happens far before the onset of phase transitions. The correlation of electron energy loss spectroscopy indicates that an early charge transfer from oxygen 2p to Mn 3d orbital is responsible.
View Article and Find Full Text PDFSmall
January 2025
State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310058, P. R. China.
Building 2D/3D heterojunction is a promising approach to passivate surface defects and improve the stability of perovskite solar cells (PSCs). Developing effective methods to build high-quality 2D/3D heterojunction is in demand. The formation of 2D/3D heterojunction involves both the diffusion of 2D spacer molecules and phase transition from 3D to 2D structure.
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