A divergent dendrimer construction methodology that employs Cu(I)-catalysed alkyne-azide cycloaddition (CuAAC) and furan-maleimide Diels-Alder (DA) "click" chemistry in a layer-by-layer fashion, is described. This synergistic approach yields dendrimers that undergo thermal disassembly via a retro-DA reaction.

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http://dx.doi.org/10.1039/b924888aDOI Listing

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