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Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand. | LitMetric

Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand.

Chem Commun (Camb)

EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, UK EH9 3JJ.

Published: March 2010

Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce(3+) cations, while the related actinide U(3+) cation is instead oxidised to U(4+) and encapsulated by the macrocyclic framework.

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Source
http://dx.doi.org/10.1039/b921132bDOI Listing

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