Transparent heat-mirror films, which transmit solar radiation but reflect ir thermal radiation, have potentially important applications in solar/thermal/electric conversion, solar heating, solar photovoltaic conversion, and window insulation. We have used rf sputtering to prepare two types of films: TiO(2)/Ag/TiO(2) and Sn-doped In(2)O(3). To characterize the properties of heat-mirror films for solar-energy collection, we define the parameters alpha(eff), the effective solar absorptivity, and epsilon(eff), the effective ir emissivity. For our Sn-doped In(2)O(3) films, alpha(eff)/epsilon(eff) is comparable to the values of alpha/epsilon reported for the leading selective absorbers. Even higher values of alpha(eff)/epsilon(eff) are obtained for the TiO(2)/Ag/TiO(2) films.
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http://dx.doi.org/10.1364/AO.15.001012 | DOI Listing |
Nanoscale
July 2021
Chemical Materials Solutions Center, Korea Research Institute of Chemical Technology, Daejeon 34114, Republic of Korea.
This study proposes a plasmonic resonance-tunable nanocomposite thin film, which applies to a color filter, heat mirror, semi-transparent color electrode, and electromagnetic shield, given that the size and structure of nanoclusters can be controlled by a sputtering power density. The structural and functional properties of silver/plasma-polymer-fluorocarbon (Ag/PPFC) nanocomposite thin films, which were sputtered by ternary composite targets, were investigated with various compositions and sputtering power densities. The growth of Ag nanoclusters of the thin film was suppressed as the sputtering power density increased due to the rich functional group of -CF- fluorine.
View Article and Find Full Text PDFWe report on HfO2/Al/HfO2 multilayer thin films for heat mirror applications prepared on corning glass substrates by electron beam evaporation. Films fabricated at a substrate temperature of 100 °C show nano-polycrystals of HfO2 embedded in a disordered lattice according to X-ray diffraction results. Atomic force microscopy revealed that HfO2/Al/HfO2 layers possess smooth surface that is appropriate for optical heat mirror applications.
View Article and Find Full Text PDFIn the optimization of multilayer stacks for various optical filtering purposes not only the thicknesses of the thin films are to be optimized, but also the sequence of materials. Materials with very different optical properties, such as metals and dielectrics, may be combined. A genetic algorithm is introduced to search for the optimal sequence of materials along with their optical thicknesses.
View Article and Find Full Text PDFTransparent heat-mirror films, which transmit solar radiation but reflect ir thermal radiation, have potentially important applications in solar/thermal/electric conversion, solar heating, solar photovoltaic conversion, and window insulation. We have used rf sputtering to prepare two types of films: TiO(2)/Ag/TiO(2) and Sn-doped In(2)O(3). To characterize the properties of heat-mirror films for solar-energy collection, we define the parameters alpha(eff), the effective solar absorptivity, and epsilon(eff), the effective ir emissivity.
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