Superhydrophobic poly(lactic acid) (PLA) fabrics are prepared by UV photo-grafting of hydrophobic silica particles possessing vinyl functional groups on the surfaces, which is a novel one-step process to provide surface with roughness as well as hydrophobicity simultaneously. For this purpose, hydrophobic silica particles with vinyl groups and average diameter of 1.51+/-0.05 microm are synthesized via a sol-gel process. The silica particles possessing vinyl groups are found to be effectively immobilized on PLA fabrics via UV photo-grafting reaction. The water contact angle of the treated PLA fabric is measured to be approximately 150 degrees, which is high enough to exhibit the Lotus effect as a result of the superhydrophobicity.

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http://dx.doi.org/10.1016/j.jcis.2010.01.024DOI Listing

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