A rutile-type porous zinc(II)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis.

Chem Commun (Camb)

Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China.

Published: February 2010

The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal-organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selective properties.

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Source
http://dx.doi.org/10.1039/b917987aDOI Listing

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