Difluoroboron avobenzone (BF(2)AVB), a simple boron complex of a commercial sunscreen product, exhibits morphology-dependent emission and mechanochromic luminescence in the solid state. When scratched, smeared, or even gently touched, the emission color of BF(2)AVB films is significantly red-shifted under UV excitation. In the rubbed regions, the fluorescence recovers slowly at room temperature or much faster with heating, resulting in a simple rewritable "scratch the surface" ink of potential commercial use.
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http://dx.doi.org/10.1021/ja9097719 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka, 577-8502, Japan.
Circularly polarized luminescence (CPL) and mechanochromic luminescence (MCL) have independently made substantial progress in recent years. However, the exploration of MCL in solid-state CPL materials, which holds practical significance, is still in its infancy. Herein, we report the MCL properties of readily accessible chiral pyrenylprolinamides bearing tert-butoxycarbonyl (Boc) or 2,2,2-trichloroethoxycarbonyl (Troc) groups.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, 999077, China.
As the investigation of high efficiency thermally activated delayed fluorescence (TADF) materials become more mature, regulating the emission properties for single organic luminescence molecules has gained increasing interest recently. Herein, the donor-acceptor compounds F-AQ comprised of fluorene and anthraquinone is reported, and it exhibits a polymorphism with muti-color emission and TADF from high-level intersystem crossing (hRISC). The photodynamics and excited-state transient species were studied by femtosecond transient absorption (fs-TA) spectroscopy.
View Article and Find Full Text PDFNature
January 2025
Department of Mechanical Engineering, Columbia University, New York, NY, USA.
Mechanical force is an essential feature for many physical and biological processes, and remote measurement of mechanical signals with high sensitivity and spatial resolution is needed for diverse applications, including robotics, biophysics, energy storage and medicine. Nanoscale luminescent force sensors excel at measuring piconewton forces, whereas larger sensors have proven powerful in probing micronewton forces. However, large gaps remain in the force magnitudes that can be probed remotely from subsurface or interfacial sites, and no individual, non-invasive sensor is capable of measuring over the large dynamic range needed to understand many systems.
View Article and Find Full Text PDFChemistry
December 2024
Department of Chemistry, Faculty of Science, Shizuoka University, Shizuoka City, Shizuoka, 422-8529, Japan.
A platinum complex equipped with 3-methylbenzofuryl groups was prepared and its crystal structure and emission properties were investigated. This platinum complex has two distinctly emissive polymorphs: a blue-emissive polymorph with low intensity and a brightly green-emissive polymorph. Upon mechanical stimulation, the blue-emitting phase is converted to green-emitting powder through a crystal-to-crystal phase transition.
View Article and Find Full Text PDFInorg Chem
December 2024
Department of Chemistry, National Taiwan University, 1, Sec. 4, Roosevelt Rd., Taipei 10617, Taiwan.
AuCl(PMe) and AuCl(PEt) were used to react with quinoline-8-thiolate (8-QNS) to give three Au(I) complexes, i.e., [8-QNS(AuPMe)]ClO (), [(8-QNS)Ag(AuPMe)]ClO (), and [8-QNS(AuPEt)]ClO (), which have been structurally determined by X-ray diffraction to show various intra- and intermolecular metal···metal contacts (i.
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