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Microsensors based on GaN semiconductors covalently functionalized with luminescent Ru(II) complexes. | LitMetric

Microsensors based on GaN semiconductors covalently functionalized with luminescent Ru(II) complexes.

J Am Chem Soc

Department of Organic Chemistry, Faculty of Chemistry, Universidad Complutense de Madrid, 28040 Madrid, Spain.

Published: February 2010

AI Article Synopsis

Article Abstract

Covalent tethering of a Ru(II) dye to gallium nitride surfaces has been accomplished as a key step in the development of innovative sensing devices in which the indicator support (semiconductor) plays the role of both support and excitation source. Luminescence emission decays and time-resolved emission spectra confirm the presence of the dye on the semiconductor surfaces, while X-ray photoelectron spectroscopy proves its covalent bonding. The O(2) sensitivity of the new device is comparable to those of other ruthenium-based sensor systems. This achievement paves the way to a new generation of integrable ultracompact microsensors that combine semiconductor emitter-probe assemblies.

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja908848cDOI Listing

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