There is a significant need to characterize and classify lignins and sulfonated lignins. Lignins have so far received a good deal of attention, whereas this is not true for sulfonated lignins. There is a clear demand for a better understanding of sulfonated lignins on a chemical as well as physical level. Many of the analytical methods have been developed with different goals in mind, for example, detection of sulfonated lignins in pulp-mill effluents, elucidation of structural changes in lignosulfonates during a pulping process, or identification of properties that may affect a formulation when sulfonated lignins are used as a dispersant. When sulfonated lignins are used in industrial applications, analytical data obtained using different techniques may be necessary to enable prediction of their behavior in the target application. In the present review, a critical discussion of established and promising analytical techniques for the characterization of sulfonated lignins is presented.
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http://dx.doi.org/10.1002/jssc.200900691 | DOI Listing |
Front Bioeng Biotechnol
January 2025
Forest Product Biotechnology/Bioenergy Group, Department of Wood Science, Faculty of Forestry, University of British Columbia, Vancouver, BC, Canada.
[This corrects the article DOI: 10.3389/fbioe.2020.
View Article and Find Full Text PDFNanoscale
January 2025
Pro2TecS - Chemical Product and Process Technology Research Center. Department of Chemical Engineering and Materials Science. Universidad de Huelva. ETSI, Campus de "El Carmen", 21071 Huelva, Spain.
This study explores the preparation of lubricating oleo-dispersions using electrospun nanofibrous mats made from low-sulfonate lignin (LSL) and polycaprolactone (PCL). The rheological and tribological properties of the oleo-dispersions were significantly modulated for the first time through the exploration of LSL/PCL ratio and electrospinning conditions such as applied voltage, distance between the tip and collector, flow rate, ambient humidity, and collector configuration. Adequate uniform ultrathin fibers and Small-amplitude oscillatory shear (SAOS) functions of the oleo-dispersions, with storage modulus values ranging from 10 to 10 Pa at 25 °C, were obtained with a flow rate of 0.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Forest Product Biotechnology/Bioenergy Group, Department of Wood Science, University of British Columbia, 2424 Main Mal, Vancouver V6T 1Z4, Canada. Electronic address:
Modern enzyme cocktails often include lytic polysaccharide monooxygenase (LPMO) as an accessory enzyme that enhances cellulose accessibility during hydrolysis. Although lignin is known to generally impede cellulose hydrolysis, previous research has demonstrated lignin's potential to act as a co-factor in boosting LPMO activity and that the negative impact of lignin limiting enzyme accessibility can be mitigated by sulfonated. When sulphonated lignin was added to microcrystalline cellulose (Avicel) the activity of the lytic polysaccharide monooxygenase (LPMO) was boosted, as determined when using a quartz crystal microbalance and dissipation monitoring (QCM-D).
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
State Key Laboratory of Materials-Oriented Chemical Engineering, Collogue of Chemical Engineering, Nanjing Tech University, Nanjing 211816, PR China. Electronic address:
In this study, demethylated-acylated enzymatic hydrolysis lignin (DAEHL) with excellent solubility in castor oil and antioxidant activities were prepared via the tandem modification strategy. First, iodocyclohexane simultaneously achieved β-O-4 breakage and hydrogenation, which enhanced the antioxidant activity of lignin. Furthermore, the acylation reaction by palmitoyl chloride increased the alkyl content in the lignin, which can improve the solubility of lignin in castor oil.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, People's Republic of China. Electronic address:
Factors influencing inhibition of lignin on the enzymatic hydrolysis have not been fully elucidated. This study aims to elucidate the effects of lignin fractionation and condensation on its inhibition on enzymatic hydrolysis in aromatic-additive-assisted acidic pretreatment using 2-naphthol (2 N), 2-naphthol-7-sulfonate (NS), and resorcinol (RS). Through simulation reactions of pretreatment and physiochemical analyses of ethanol-extractable lignins (ELs) and cellulolytic enzyme lignins (CELs) from pretreatment, it was observed that 2 N addition in the acidic pretreatment could suppress lignin condensation.
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