Graphene is considered to be a promising candidate for future nanoelectronics due to its exceptional electronic properties. Unfortunately, the graphene field-effect transistors (FETs) cannot be turned off effectively due to the absence of a band gap, leading to an on/off current ratio typically around 5 in top-gated graphene FETs. On the other hand, theoretical investigations and optical measurements suggest that a band gap up to a few hundred millielectronvolts can be created by the perpendicular E-field in bilayer graphenes. Although previous carrier transport measurements in bilayer graphene transistors did indicate a gate-induced insulating state at temperatures below 1 K, the electrical (or transport) band gap was estimated to be a few millielectronvolts, and the room temperature on/off current ratio in bilayer graphene FETs remains similar to those in single-layer graphene FETs. Here, for the first time, we report an on/off current ratio of around 100 and 2000 at room temperature and 20 K, respectively, in our dual-gate bilayer graphene FETs. We also measured an electrical band gap of >130 and 80 meV at average electric displacements of 2.2 and 1.3 V nm(-1), respectively. This demonstration reveals the great potential of bilayer graphene in applications such as digital electronics, pseudospintronics, terahertz technology, and infrared nanophotonics.
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http://dx.doi.org/10.1021/nl9039636 | DOI Listing |
Discov Nano
January 2025
Physics Department/Faculty of Science, Sana'a University, Sana'a, Yemen.
The study highlights the significant effects of Zn ions concentration on the optical properties of BaNiZnFeO ferrites, emphasizing the tunability of the band gap through Zn doping and explores their potential to enhance their optical properties. The barium-nickel ferrite powder, with the composition BaNiZnFeO, was synthesized using the ceramic method. The effects of Zn doping were analyzed using X-ray diffraction (XRD) and UV‒visible (UV-Vis) spectroscopy.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Photonics and Nanoelectronics, and BK21 FOUR ERICA-ACE Center, Hanyang University, Ansan 15588, Korea.
Colloidal quantum-dot light-emitting diodes (QD-LEDs) have been significantly improved in terms of device performance and lifetime by employing zinc oxide (ZnO) as an electron transport layer (ETL). Although atomic layer deposition (ALD) allows fabrication of uniform, high-quality ZnO films with minimal defects, the high conductivity of ZnO has hindered its straightforward application as an ETL in QD-LEDs. Herein, we propose fabrication of Al-doped ZnMgO (Al:ZnMgO) ETLs for QD-LEDs through a supercycle ALD, with alternating depositions of various metal oxides.
View Article and Find Full Text PDFHeliyon
December 2024
Department of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia, Bangladesh.
Hematite (α-FeO) nanoparticles have been synthesized from waste source of iron which contains a prominent amount of iron (93.2 %) and investigated the effect of low temperature calcination. The two-step synthesis method involved preparing ferrous sulfate through acid leaching process followed by oxidation and calcination at temperatures ranging from 200 to 400 °C to produce the desired α-FeO in nano form.
View Article and Find Full Text PDFThe potential application of materials referred to as perovskite hydrides in hydrogen storage - a crucial element of renewable energy systems - has sparked a great deal of interest. We use density functional theory (DFT) to investigate the structural, formation energy, hydrogen storage, electronics, thermoelectric and elastic properties of NaXH (X = Be, Mg, Ca, and Sr) hydrides. The band gap is calculated using WC-GGA and WC-GGA+mBJ potentials.
View Article and Find Full Text PDFACS Omega
December 2024
Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran 1458889694, Iran.
We present a novel approach for enhancing photocatalytic efficiency by developing polyaniline (PANI) and polyindole (PIN)-coated TiO nanotubes (TNT) through a combination of chemical oxidation and hydrothermal processes. The PANI-PIN coating was systematically applied to both the internal and external surfaces of the nanotubes to enhance the photocatalytic active sites and optimize pollutant adsorption. The dual-coated structure enhances the interaction with pollutants, facilitating a more efficient degradation of 4-nitrophenol (4-NP) when exposed to visible light.
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