Crystal chemical data of high- (HT) and low-temperature (LT) modifications of lithium argyrodites with the compositions Li(7)PCh(6) (Ch=S, Se), Li(6)PCh(5)X (X=Cl, Br, I), Li(6)AsS(5)Br, and Li(6)AsCh(5)I (Ch=S, Se) based on single-crystal, powder X-ray (113 K
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http://dx.doi.org/10.1002/chem.200902470 DOI Listing Publication Analysis
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Adv Mater
January 2025
Materials Science and Engineering Program, Walker Department of Mechanical Engineering and Texas Materials Institute, The University of Texas at Austin, Austin, TX, 78712, USA.
Anode-free all solid-state batteries (AF-ASSBs) employ "empty" current collector with three active interfaces that determine electrochemical stability; lithium metal - Solid electrolyte (SE) interphase (SEI-1), lithium - current collector interface, and collector - SE interphase (SEI-2). Argyrodite LiPSCl (LPSCl) solid electrolyte (SE) displays SEI-2 containing copper sulfides, formed even at open circuit. Bilayer of 140 nm magnesium/30 nm tungsten (Mg/W-Cu) controls the three interfaces and allows for state-of-the-art electrochemical performance in half-cells and fullcells.
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December 2024
LiB Materials Research Group, Research Institute of Industrial Technology and Science (RIST), POSCO Global R and D Center, Sondohwahak-ro 100, Yeonsu-gu, Incheon, 21985, Republic of Korea.
The demand for all-solid-state batteries (ASSBs) featuring credible LiPSCl argyrodite (LPSCl) electrolytes is increasing, driving interest in exploring suitable current collectors for ASSBs. Copper (Cu), used as a current collector in traditional lithium-ion batteries, exhibits significant instability in LPSCl-ASSBs. In this study, the effectiveness of iron (Fe) is systematically investigated as an alternative current collector in LPSCl-ASSBs and compare its performance to that of Cu.
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November 2024
Solid State Batteries Research Center, GRINM (Guangdong) Institute for Advanced Materials and Technology, College of New Energy and Electrical Engineering, Foshan, Guangdong, 528051, P. R. China.
Lithium dendrite growth has become a significant barrier to realizing high-performance all-solid-state lithium metal batteries. Herein, an effective approach is presented to address this challenge through interphase engineering by using a cross-linked polyamide (negative electrostatic potential) that is chemically anchored to the surface of LiPSCl (positive electrostatic potential). This method improves contact between electrolyte particles and strategically modifies the local electronic structure at the grain boundary.
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November 2024
State Key Laboratory of Advanced Electromagnetic Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China.
Chlorine-rich lithium argyrodite is considered as a promising superionic conductor electrolyte, but its practical application is limited due to poor air stability and instability toward lithium metal. In this work, BiF is proposed as a multi-functional dopant for electrolyte modification, and the effects on the ionic conductivity, air stability, critical current density, and electrolyte/Li metal interfacial stability are studied. The results show that the doped electrolyte LiPBiSClF (LPBiSClF) still maintains a relatively high ionic conductivity of 5.
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October 2024
Department of Chemistry, Colorado School of Mines, Golden, Colorado 80401, United States.
Halide argyrodite solid-state electrolytes of the general formula LiPS exhibit complex static and dynamic disorder that plays a crucial role in ion transport processes. Here, we unravel the rich interplay between site disorder and dynamics in the plastic crystal argyrodite LiPSCN and the impact on ion diffusion processes through a suite of experimental and computational methodologies, including temperature-dependent synchrotron powder X-ray diffraction, AC electrochemical impedance spectroscopy, Li solid-state NMR, and machine learning-assisted molecular dynamics simulations. Sulfide and (pseudo)halide site disorder between the two anion sublattices unilaterally improves long-range lithium diffusion irrespective of the (pseudo)halide identity, which demonstrates the importance of site disorder in dictating bulk ionic conductivity in the argyrodite family.
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