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Indirubin-3'-oxime as a dual-action agent: mitigating heat-induced male infertility in and inhibiting soluble epoxide hydrolase.
J Enzyme Inhib Med Chem
December 2025
Department of Biology Education, Teachers College and Institute for Phylogenomics and Evolution, Kyungpook National University, Daegu, Republic of Korea.
This study investigated the potential of the indirubin-3'-oxime (I3O) compound to mitigate temperature-induced male infertility in . Elevated temperatures significantly reduced egg-hatching rates, but I3O supplementation improved these rates, suggesting it can partially restore fertility under heat stress. Additionally, I3O was found to inhibit soluble epoxide hydrolase (sEH), an enzyme involved in the metabolism of epoxyeicosatrienoic acids, which are vital for reproductive health.
View Article and Find Full Text PDFUltrafast Preparation of High-Entropy NASICON Cathode Enables Stabilized Multielectron Redox and Wide-Temperature (-50-60 °C) Workability in Sodium-Ion Batteries.
Adv Mater
January 2025
MOE Key Laboratory for UV Light-Emitting Materials and Technology, Department of Physics, Northeast Normal University, Changchun, 130024, P. R. China.
Avoiding severe structural distortion, irreversible phase transition, and realizing the stabilized multielectron redox are vital for promoting the development of high-performance NASICON-type cathode materials for sodium-ion batteries (SIBs). Herein, a high-entropy NaVFeTiMnCr(PO) (HE-NaTMP) cathode material is prepared by ultrafast high-temperature shock, which inhibits the possibility of phase separation and achieves reversible and stable multielectron transfer of 2.4/2.
View Article and Find Full Text PDFTwo-dimensional inverse double sandwich CoB: strain-induced non-magnetic to ferromagnetic transition.
Phys Chem Chem Phys
January 2025
Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Materials Chemistry and Service Failure, Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
A full-scale structural search was performed using density functional theory calculations and a universal structural prediction evolutionary algorithm. This produced a lowest energy two-dimensional (2D) CoB structure. The CoB-1 global minimum structure has unusual inverse double sandwich features.
View Article and Find Full Text PDFAdvancing Oxygen Evolution Catalysis with Dual-Phase Nickel Sulfide Nanostructures.
Energy Fuels
January 2025
Department of Gaseous Electronics (F6), Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia.
The production, conversion and storage of energy based on electrocatalysis, mainly assisted by oxygen evolution reaction (OER), plays a crucial role in alkaline water electrolyzers (AWEs) and fuel cells. Nevertheless, the insufficient availability of highly efficient catalyst materials at a reasonable cost that overcome the sluggish electrochemical kinetics of the OER is one of the significant obstacles. Herein, we report a fast and facile synthesis of vapor phase deposition of dual-phase nickel sulfide (Ni-sulfide) using low-temperature annealing in the presence of HS and demonstrated as an efficient catalyst for OER to address the issues with sluggish electrochemical kinetics.
View Article and Find Full Text PDFRF Heating Effects in CEST NMR with Hyperpolarized 129Xe Considering Different Spin Exchange Kinetics and Saturation Schemes.
Chemphyschem
January 2025
Deutsches Krebsforschungszentrum, Translational Molecular Imaging, Im Neuenheimer Feld 223, 69120, Heidelberg, GERMANY.
Chemical exchange saturation transfer (CEST) improves the sensitivity of NMR but depending on the spin exchange kinetics, it can require substantial RF energy deposition to label magnetization. Potential side effects like RF-induced heating may occur and must be monitored. Here, we explore the parameter space considering not only undesired heating but efficient CEST build-up (depolarization rate), spectral resolution (line width), and subsequent effects like changes in chemical shifts of CEST responses must be considered, too.
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