AI Article Synopsis
- The hydrothermal reaction involves the combination of copper sulfate, 1,2-benzenedicarboxylate, and a bidentate ligand, resulting in a two-dimensional metal-organic framework.
- The framework is denoted as {[Cu(5)(bime)(mu(3)-OH)(2)(phth)(4)](H(2)O)(2)}(n) and features a pentanuclear copper(II) cluster structure.
- This metal-organic framework exhibits significant ferromagnetic interactions, indicating potential applications in magnetic materials.
Article Abstract
The hydrothermal reaction of CuSO(4), 1,2-benzenedicarboxylate (phth), and 1,2-bis(imidazol-1-yl)ethane (bime) yields the two-dimensional metal-organic framework {[Cu(5)(bime)(mu(3)-OH)(2)(phth)(4)](H(2)O)(2)}(n) (1), which is based on the pentanuclear copper(II) cluster [Cu(5)(mu(3)-OH)(2)(phth)(4)] and shows dominant ferromagnetic interactions within the pentanuclear cluster.
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| http://dx.doi.org/10.1021/ic902404b | DOI Listing |
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